Long-tailed macaque monkeys have a reputation for knowing how to find food — whether it be grabbing fruit from jungle trees or snatching a banana from a startled tourist.
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| One of the catalyst formulations has run in the MEA for more than 7,300 hours. Click to enlarge. |
A research team led by 3M is developing high-performance fuel cell cathodes (catalyst and support) based on 3M’s nanostructured thin film (NSTF) catalyst technology platform. A membrane electrode assembly (MEA) featuring one formulation of an NSTF catalyst has operated for more than 7,300 hours, significantly exceeding the Department of Energy 2015 target of 5,000 hours (equivalent to about 150,000 miles).
Mark Debe from 3M presented the status of the project at the DOE Hydrogen Program annual merit review, running this week in Washington, DC. Partners in the four-year project, which is now 30% complete, include Dalhousie University, JPL and Argonne National Laboratory.
| DOE Electrocatalyst/MEA Targets | ||
|---|---|---|
| Parameter | 2010 | 2015 |
| Lifetime Hours, > 80°C | 2,000 | 5,000 |
| Mass Activity (A/mg) | 0.44 | 0.44 |
| PGM (g/kW rated) | 0.3 | 0.2 |
| Performance (W/cm2) @ rated @ 0.8V |
1 0.25 |
1 0.25 |
To achieve the durability results, research team used a PtCoMn catalyst with 0.2 mgPt/cm2 on a mechanically stabilized but neat 3M ionomer to achieve the durability results. An earlier effort with the same catalyst but on a non-chemically or mechanically stabilized 3M PEM showed an average lifetime of about 3,500 hours—about a 7x gain in lifetime to failure (defined as OCV < 0.8V) versus the results produced by a dispersed Pt/C catalyst.
Other results of the work with NSTF catalysts on which Debe reported include:
Improved catalyst roll-good fabrication and membrane integration. The team produced current density improvements by reducing the microstructured feature size of the NSTF roll-good substrate.
The NSTF catalysts were resistant to Pt dissolution and corrosion. The catalysts showed a mass activity loss under a DOE test protocol of about 13%. DOE’s target for this is < 60%.
Dalhousie University is working to determine new advanced catalysts by using compositional spread screening. Sixty-four-electrode arrays of think film catalysts are deposited onto NSTF whiskers, made into MEAs at 3M, and tested at Dalhousie. More than 60 libraries have been fabricated and tested to date.
Eight new catalyst material sets from one configuration were found to have higher initial surface area compared to pure Pt control materials. Most of these indicated surface area increases dependent on the mole fraction of the additive compound or element. Five of these indicated higher surface areas after 3,000 CV cycles than the Pt controls.
Future work on this project is focused on three main areas:
Mass activity gain. The team will continue to fabricate and test new catalyst compositions, structures and processes for a specific activity gain of 2x over current NSTF baseline, targeting no loss of durability under most severe accelerated test. The best resulting candidates will be moved to 50 cm2 sized electrodes.
The team is also seeking to achieve a more than 100% gain in catalyst surface area over the current NSTF baseline without loss of specific activity or durability.
Durability improvement. Reduce by 50% any losses in surface area, activity or mass transport over-potential.
Water management improvement. The team is seeking to deliver more effective liquid water transport at low temperatures without compromising high-temperature performance under dry conditions.
| Current project status against targets. Click to enlarge. |
Enphase Energy on Monday released a solar power system that takes a dramatically different approach to harnessing energy from the solar panels.

With an inverter on every solar panel, owners can view performance of each individual module via the Web.
(Credit: Enphase Energy)The start-up company, which raised initial earlier this year, ...
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